By 2050, most vehicles
will need to be electrically propelled, with a battery to store energy or an
on-board hydrogen fuel cell to generate electricity, if emission targets set by
governments are to be met.
That
is the conclusion of a team responsible for penning Towards
Sustainable Road Transport published by Elsevier.
The three authors are senior research
chemists who have spent their professional careers working in the fields of
energy and electrochemistry – and the development of battery systems. So a
report expressing a bright future for electric vehicles might, perhaps in the
circumstances, be expected.
Over 300 pages of information describe the
growth and technical development of road vehicles during the 20th century,
and the state-of-the-art power sources and advanced vehicle designs now needed
to meet the 80 per cent reduction required in global emissions over the next 35
years, and needed to protect the next generation.
“Over the past 25 years, the auto industry
has reduced its greenhouse gas emissions by 20 per cent from a 1990 baseline,
which is less than 1 per cent a year,” says Patrick Moseley, president emeritus
of the Advanced Lead–Acid Battery Consortium (ALABC). “Over the next 35
years, the industry will have to sustain the 2 to 3 per cent annual reduction
that it is now achieving. That is a tall order.”
Moseley’s co-authors are Ronald Dell, former
head of applied electrochemistry at the UK Atomic Energy Authority and David
Rand, a former chief research scientist of the Commonwealth Scientific and
Industrial Research Organisation (CSIRO) of Australia.
Their first edition book focuses attention
on road transport, a key aspect of human activity among the many sectors –
including agriculture, industry and power – that require attention if
sustainable development on a global scale is to be achieved.
“Our work examines the prospects for an
evolution of the global transport systems, which currently consumes
irreplaceable resources and degrades the environment, towards one with a modus
operandi that
will be both supportable and benign,” says Dell. “This is a considerable
challenge. The global fleet of motor vehicles of all types, including
two-wheelers, is now around one-and-a-half billion, of which one billion are
cars. This is expected to reach two billion soon after 2020, with a rapid
increase in the number of internal combustion engine vehicles (ICEVs)
anticipated in China and India, which is an understandable increase given the
aspirations of these two enormous populations.”
Conflicting
“Automotive
manufacturers face the conflicting demands of customers for vehicles with
ever-improved performance, safety and comfort – but without any appreciable
increase in cost,” says Rand. “This is being resolved through advances in
vehicle design and in particular through refinement in propulsion technology.
The trend is towards smaller internal combustion engines augmented by
intelligent electrification with no decrease in power; this combination being
especially effective in reducing both emissions and fuel consumption.”
All three authors have been heavily involved
throughout their careers in electrochemistry and the development of advanced
battery designs and power sources. So not surprisingly they express their
views on numerous advanced battery chemistries and super-capacitors being
considered for use in road vehicles.
“Batteries in different categories of road
vehicle are required to perform widely disparate duty cycles,” says Moseley.
“In a conventional ICEV, the starting, lighting and ignition battery is
maintained at almost a full state-of-charge (SoC) of between 85 and 90 per
cent. In battery electric vehicles (BEVs), the SoC of the cells declines
throughout the journey from 100 to 20 per cent, and once their chemical energy
is depleted they have to be recharged for the next journey,” added Dell.
“In hybrid electric vehicles (HEVs)
such as the Toyota Prius and especially the new breed of low-voltage (48V)
super hybrids from Audi and Kia and other carmakers, the batteries are subject
to a critical high-rate partial state-of-charge (HRPSoC) operation of between
50 and 70 per cent,” Dell noted.
The above duty cycles explain why
lithium-ion batteries, with their high-voltage cells and high specific energy
(Watt-hours per kilogram), are currently utilised for pure electric vehicles
despite their high cost and need for cooling, while the recent breakthrough of
advanced lead-carbon batteries is better suited to both stop-start and 48V
vehicles. The book’s co-authors confirm that even though the search for
more advanced battery chemistries continues, there appears to be little
prospect in the short term of finding a battery system that can provide a BEV
driving range between charges of much more than 150 miles (240 km), while
withstanding rapid recharging for a satisfactory life and being manufactured at
a competitive cost.
“It could be 20 years before possible
next-generation lithium-air batteries make it out of the laboratory and into
the car,” declared Rand.
Given the limitations of BEVs and doubts
about developing an entirely new and affordable battery with satisfactory
performance and safety, the book describes why the automotive and transport
industry meanwhile has turned its attention to hybrid vehicles, in which a
battery powered motor-generator is combined with a heat engine to
provide a more efficient propulsion system without subjecting motorists to
‘range anxiety’.
“Hybrids do not eliminate tailpipe
emissions, but they do reduce them by making use of the hydrocarbon fuel more
efficiently and, crucially, the vehicles do not suffer from the range limitations
that beset BEVs,” noted Dell. “Hybrids are also in tune with progressively
tighter emissions legislation, because there is a full range of designs
available from the simplest stop-start and 48 volt forms, with the least
additional cost, through to the most expensive hybrids. Thus it is
possible to introduce vehicles with increasing degrees of electrification and
cost/benefit improvements.”
The book also refers to Rand’s involvement
in over 20 years of research undertaken by CSIRO that has contributed to the
improvements gained in the performance, power capability and cycle-life of
valve-regulated lead-acid (VRLA) batteries.
Recently, CSIRO has provided a means for
overcoming the problems of the HRPSoC duty cycle through the invention of a
radical new design of VRLA battery, in which the negative plate is protected
from the deleterious effects of high-rate charge and discharge by sharing the
current with an integrated super-capacitor. The innovative configuration
of the CSIRO Ultra-Battery™ combines a VRLA cell with an asymmetric super-capacitor
in a single unit without the need for extra electronic control.
“This technology is less costly, is more
compact and occupies less volume than the combination of a conventional battery
in parallel with a conventional super-capacitor,” says Moseley. “As part
of its continuing research programme, the ALABC has fitted prototype units
constructed by the Furukawa Battery Company in Japan to a Honda Insight, which
successfully completed 100,000 miles (160,000km) at Millbrook proving ground in
the UK.
“Interestingly, an increase in the quantity
of carbon in the negative active-material can promote a significant increase in
battery life under HEV duty. An extensive test on East Penn’s licensed design
of Ultra-Battery was able to reach 167,000 miles (267,000km) in the
laboratory.
The ALABC has since completed another
150,000 miles of real world driving in Arizona in a Honda Civic Hybrid - a
particularly demanding HRPSoC operation – and continues to run the vehicle to
determine the full lifetime of the batteries. So far, they show no performance
degradation and remarkably the individual battery voltages of the pack are
beneficially converging as they age – though as yet we know not why.”
Several major car companies are
now actively working towards introducing lead-carbon batteries into the
abovementioned stop-start and 48V mild super hybrids. For instance, Kia has
announced its preference for this new battery chemistry over a
lithium-ion alternative because: ‘lead-carbon cells require no active cooling,
are more readily recycled at the end of the vehicle’s life, and can function
more efficiently at sub-zero temperatures’.
The assistance of Dr Jacquie Berry,
Professor Dame Julia King and Sir Robert Watson in the preparation of this
comprehensive tome is acknowledged by three authors.
Dame Professor Julia King is Vice-Chancellor
of Aston University. In 2007 she was appointed by Gordon Brown, the then UK
Chancellor of the Exchequer, to lead a review of future vehicle and fuel
technologies that could help to reduce carbon emissions from road transport.
One valid question might be: How and where
will the electric power be generated for so many EVs?
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